There's a lot of discussion on this "probing the coolant" in the annals of the Brickboard, and just as you see, a lot of misconceptions.
The (original?) article was in a car magazine, I think, and not 240 Volvo specific, but the idea was to find sources of potential differences on metal parts of the cooling system, not to dip probes into the coolant and find out where the nickel plating on your meter probe tip falls in the galvanic series. It went on to suggest re-bonding of things like block to head, radiator, and heater core, and of course, maintaining the pH in the coolant.
Ted is proposing we check with and without the electrical system in operation, as that would be an active contributor not "fixed" by coolant maintenance. The 240 heater core is isolated, the rad is isolated, but the automatic has this very thin, electrically connected brass heat exchanger immersed in the coolant (boy do I dread when that baby fails), and the Ranco heater valve through its mechanical cable. So if poor grounding causes voltages to appear across those items, the measurement would clearly be changed by disconnecting the car's electrical system.
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Art Benstein near Baltimore
Never test the depth of the water with both feet.
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