I have access to VADIS (Volvo software) and found your EVAP valve on the driver's side of the fan housing at the front of the car. It is attached about 3/4 of the way up on the housing with a mounting of its own and looks rectangular with nipples at right angles from each other. It looks easy to replace. Each nippple should be covered with a hose. One of the hoses comes from/off of the charcoal cannister located under the heat deflector plate near the fuel tank in the rear of the car. The other appears to go on to the front of the engine. Problem is that on your car, I also see an EVAP purge valve located under the heat deflector, almost attached to the fuel pump. Let's hope that if you need to replace a purge valve, that's not the one. VADIS lists the first EVAP valve I mentioned as part #9470775 for '01's. I have a diagram I can send you if you have an email. If you look that part number up at http://www.foreigncarpartsonline.com/ you'll find a description of it and price at $22.59. Seems like it's a fairly cheap gamble to me. Anyway, hopefully this information helped.
Edit: Here you can see a picture (diagram) of the purge valve that may help you in locating it on your car: http://www.thevolvosite.com/shop/index.php?Cat=1015&car_model=S80
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1998 S70 T5 Emarald Green Metallic, 2004 V70 2.5T Ruby Red, Previous Owner of Black '94 850 Turbo Wagon. My cars have been running so well lately they've got me worried.
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